To change options for what happens when you are on a Teams call and a new call comes in, make changes to the options inside Settings as shown below.
From inside Teams:
Click Profile Name/Picture in the upper right.
Choose Manage Account
Choose Calls in the left column
Change the "When you're in a call and receive a call" option to what desired option is.
Options:
- Let new calls ring me (rings through, if not answered - default is Voicemail)
- Play a busy signal (busy signal - not redirected to Voicemail)
- Redirect as if call is unanswered (see option above - default is Voicemail)